Craft · 6 pages · 12 min

Why stainless steel resists rust

Enough chromium in the alloy grows a thin oxide film that blocks rust and heals in air.

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From the opening

Stainless steel resists rust because it contains enough chromium, more than about a tenth of the alloy, to cover itself with a very thin chromium oxide. That film clings, blocks oxygen and water from reaching fresh iron, and forms again after a scratch as long as oxygen is there to rebuild it. The opening covers chromium grows a passive oxide, the film repairs itself in air, and salt can still open pits.

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Inside

  • Chromium grows a passive oxide
  • The film repairs itself in air
  • Salt can still open pits
  • Plating only hides another core
  • Where the idea stops applying
  • A distinction worth keeping

Sources

  • Chromium passive film on stainless steel
  • Early chromium stainless alloys