Science · 6 pages · 12 min

How distillation separates a liquid mixture

The vapor is richer in the component that boils more easily, and condensing it keeps the split.

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From the opening

Distillation separates a liquid mixture by boiling it and condensing the vapor, which is richer than the pot in whichever component evaporates more readily. One collection of that vapor is a step toward the more volatile liquid, not a filter that caught the other one. The opening covers vapor richer than the pot, why a column repeats the step, and azeotropes that stop the split.

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Inside

  • Vapor richer than the pot
  • Why a column repeats the step
  • Azeotropes that stop the split
  • Boiling cooler under vacuum
  • Where the idea stops applying
  • A distinction worth keeping

Sources

  • Vapor-liquid equilibrium in distillation
  • Fractional distillation and azeotropes